YES! That is my all time favorite Jean-Luc moment, ever, out of all of them, and the line about having to bow to the absurd is my all time favorite Jean-Luc line. It's the first time we see him truly LAUGHING and Riker being like "that's the LAST thing I expected" just adds to the whole moment. I absolutely LOVE how it's the result of the whole absurdity of what has happened so far and I love how he just walks away and tries to compose himself but can't manage and then just laughs like "Imma just go with it now, I don't know wtf is happening anymore but hey, I'm here for it, lmao". It's such a cute moment and it makes me love him even more because he's utterly adorable when he stands there and just... laughs.
I love the "OH NO" on Jean-Luc's face when Data is all like "sir"... his "oh no he has me now, doesn't he, he's gonna ask me about things I don't want to talk about" face adds to the whole scene.

I love his dry sense of humor SO MUCH. Especially when Q appears - I love the moment when Q whines about having been sent to the Enterprise as punishment by the Q Continuum and Jean-Luc deadpans "And punish US as well, it would seem"

or when Riker goes on about how he feels like "an idiot" for not realizing what Q was trying to do when he gave him Q powers and Jean-Luc just sits there and looks at him and says "quite right, so you should" - SAVAGE, Jean-Luc, SAVAGE

ah I could go on for hours. I adore Jean-Luc's sense of humor so much, and with him it's always the little moments that stand out, he isn't overly loud in a funny way, it's often just the way he delivers a line, or sometimes even just his face - I HOWL with laughter when Troi makes it clear to him that HE should be the one to take care of Jono and you can literally SEE the panic creeping into his face.