If Chateau Picard even makes a synthehol edition, it would be several years before the wine would have matured enough to be drunk.
Besides, Captains always have their own stash of real alcoholic beverages, even in the era when sythehol was common, Picard had real Aldebaran whiskey, Sisko managed to get access to Klingon Blood Wine, and whatever he was drinking while making his log entry in Pale Moonlight.
Besides, Captains always have their own stash of real alcoholic beverages, even in the era when sythehol was common, Picard had real Aldebaran whiskey, Sisko managed to get access to Klingon Blood Wine, and whatever he was drinking while making his log entry in Pale Moonlight.