To me the two DS9 characters who fit into that category were Jadzia and Sisko. Early Bashir as well, when his whole character consisted just of "wanting to bone Jadzia"
Well, I would say Bashir was rather dull, but I thought "old man" Jadzia was definitely charming and interesting. Sisko was just the straight up intense boss. Here never seemed an amazingly interesting character, but he never bored or annoyed me either. (I think there was only Bashir who did that, but he did act as a great character for others to play off of).
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