That suggest quite strongly that the Science Officer is ALWAYS the XO. Doesn't that seem a little ridiculous to you? Not well-thought-out? Only one path to command, and it runs thru Science Officer.
Did Kirk have to pull a stint as Science Officer on a ship, before getting his command?
I suppose it could be just for ships on scientific/exploration or "UESPA" missions. I have wondered if the "blue shirts" were actually civilians at some earlier point, and that the Science Officer was almost a liaison to the military side, and him being 2iC was a holdover from those days. I'm OK with chucking the idea like BillJ says, but Will Decker was a qualified Science Officer in TMP, and Sulu was working in astrosciences before he went to the helm, so a science officer background doesn't seem to rule anyone out of higher command.
How can a non Vulcan do two difficult jobs well, even assuming (nominally) a shift as Science Officer and another as Exec.
How could a Vulcan, really? Throughout Trek there seems to be an idea that XO is not a full-time job, and they can pull watches and do other things besides.