I really don't know all of the movies well enough to rank them all. So I'll just list the ones I really like and the ones I really don't like (everything else is either in the middle or I don't remember it well enough).
Really like (in chronological order):
Goldfinger (1964) - An absolute Bond classic. Connery shines, and Gert Fröbe provides a more than worthy adversary.
You Only Live Twice (1967) - I really love the settings and the feel of this one. Also, is there no way not to like the huge crater in the volcano?
Live and Let Die (1973) - This one's kind of weird and certainly not PC (but then, very few Bond movies are

) but it's a good start for Moore, I think, and offers some really good suspense and action.
The Spy Who Loved Me (1977) - This is one of the best Moore Bonds, I think. It's got a great villain with some nice toys (gotta love the tanker and the underwater base

), lots of great action as well as tons of fun.
Moonraker (1979) - This is one silly, silly movie. But I just a kick out of it every time. It's just fun all the way, not to be taken seriously at all.
Tomorrow Never Dies (1997) - Easily my favorite Brosnan Bond. I think this one succeeds largely thanks to the fantastic Michelle Yeoh and her chemistry with Bond. Finally, you've got a Bond 'girl' who's capable and really adds to the movie. It can drag a bit in parts and the villain (though I do really like Pryce as an actor) doesn't quite convince me, but it still manages to be engaging, fun and far, far more up-to-date than the two Brosnan Bonds that followed which were stuck somewhere in the middle ages.
Casino Royale (2006) - Very exciting, very well made, with a terrific new Bond. Bond has finally reached this day and age.
Really dislike:
On Her Majesty's Secret Service (1969) - I don't mind Lazenby as Bond, but I simply feel this is a pretty bad movie. One of the worst things was the constant flow of bad one-liners, I felt, but that's certainly not the only problem.
Diamonds Are Forever (1971) - One of Connery's weakest offerings, I think. The move to the US just doesn't really work here, I think. This film just seems to lack the typical Bond film.
Never Say Never Again (1983) - Connery should have said "Never" to this one, I think. I don't remember anything redeeming about this one.
License to Kill (1989) - I could never, ever get through this one. I'm not sure if I just can't take Dalton as Bond or whether it's just the movie itself. I think it's the latter, really.
The World Is Not Enough (1999) - Boring, plain boring. This movie seems to go nowhere, provides nothing but mindless explosions at every corner (you're always left to wonder where those barrels came from...) and rotten one-liners. Naming a character to suit a stupid one-liner is NOT a good idea.
Die Another Day (2002) - A horrible, horrible mess. Just totally, TOTALLY over the top in a way even Moonraker wasn't. And unlike the latter which didn't take itself seriously, this one just seems so full of itself which makes it even worse. Add in a terrible Halle Berry, an attitude towards women that's worse than even the movies of the 60's and just tons of bad one-liners and you've got what I think is easily the worst Bond movie ever.
Just a quick note concerning actors. I think it's a HUGE shame that Brosnan was so unfortunate with his Bond movies. Other than Tomorrow Never Dies - which I really like - there's only one pretty mediocre offering (Goldeneye), one really bad one (The World Is Not Enough), and what's probably the worst Bond movie ever (Die Another Day).
I think Brosnan was perfect for the Bond he played (Craig's is a very different but also great Bond) but got really unlucky. It's a shame he couldn't get out of that TV show he was in some years ago. He might have ended up with a set of really good films.