Chakotay makes the impression that he is not the kind of guy who is mad about the holodeck.
Having said that, he's always been interested in archaeology ... so he might have a few holoprogrammes about archaeological digs. And just to stay on top form, he occasionally runs a boxing simulation.
Harry obviously enjoys adventure holonovels so in addition to Beowulf and Chaotica he probably runs anything to do with adventure. Robin Hood and William Tell ... or something more modern, like Captain Kirk's (or any other Starfleet Captain's) daring exploits.
Seven must run programmes that are not irrelevant to her development as a human being. She probably does research in areas like cooking, interior design, floral design, social behaviour .... nothing that's particularly entertaining but useful for her development.
Tuvok might run Sherlock Holmes (or Poirot) quite a lot, which would match the Vulcan definition of "entertainment". He basically uses these programmes to develop his investigation skills so that he can become a better detective. I guess that he is basically into developing holodeck programmes rather than actually running them. Most of these programmes must revolve around crew discipline and efficiency like physical and psychological training programmes, battle simulations etc. After what happened to them in BASICS, I'm sure he started developing a survival simulation. He might have written one for integrating the Equinox crew into the Voyager crew and one for the three stray sheep in GOOD SHEPHERD. He must also have a programme, which he uses himself, when he experiments with new plant species. So even though he doesn't make the impression he is very much into the holodeck, he probably spends most of his time there developing this and that, perfecting one holographic simulation after another.
B'Elanna seemed to enjoy the Paxau simulation - who wouldn't? -, we were also able to witness how she had created a kind of toy boy for herself. She also goes with Tom to various other resorts like Tahiti and the one in DRIVE when the Doctor also wants to join them because there's a championship golf course there. So she must enjoy anything recreational where the temperatures are not too low. Although we occasionally see her in some violent programmes (the Klingon programme in DAY OF HONOR and the Cardassian one in EXTREME RISK), she doesn't enjoy those situations too much. They both have to do with either her Klingon background or her being a Maquis and since both of these are connected to pain, she must generally want to avoid violent simulations like those. So she must have created a plethora of environments where she can just enjoy the sunshine and relax.
To counterbalance all the science (and the technobabble

) she has to deal with, Janeway must have created various literature and history programmes. In addition to Gothic fiction and Leonardo da Vinci, she must be spending her time with Charles Dickens, Isaac Newton, ancient Greek philosophers and all sorts of other culturally important people from Earth and from alien cultures like Vulcan philosophers and Romulan playwrights, etc. At the same time she also loves Velocity and we've seen that she has forgotten a lot about tennis (how can you even be so bad at tennis when you're so good at velocity?), so she must use different sports programmes as well - on a regular basis.
I'm sure the Doctor has a wide range of programmes in which his ego is massaged and put on pedestal, in all of which, needless to say, he is the main character. So he must sing operas all the time, he must play the most important male protagonists of the outstanding dramas of world literature, such as Hamlet, Faust, Oedipus etc - and of course, other characters from other Federation literature as well. In addition, he must organise tours to galeries and museums, and on these occasions he plays the role of the knowledgeable tour guide, enthralling his audience with his amazing knowledge in a wide range of subjects.
Tommyboy is the (not yet crowned

) King of the Holodeck and has an endless selection of programmes that revolve around one central theme: fun. These might be relaxing like Chez Sandrine's or silly like the Chaotica simulation - the main idea is that they are fun, fun and ... fun.

He surely makes the impression he has a few sex programmes as well - if he does, I'm sure he is not the only crew member to use them. In addition, he as well as the Doctor spend a lot of time writing holonovels (rivalry?) which they try to publish anywhere they can. Once they realize that they are both capable of writing good quality stuff, they start cooperating and write an adventurous novel about some kind of conflict in which the main player saves the day while a holographic Doctor's versatile skills turn out to be an invaluable help to the otherwise wacky protagonist.
I'm sorry to say that I have no idea if Kes and Neelix use the holodeck or not. They seem to be content with their lives on Voyager as they are ... so they might not do much on the holodeck. Although occasionally it is perhaps here that Neelix develops his cooking skills (which look really like they are in need of development ...) and perhaps it is here that Tuvok occasionally teaches Kes to meditate.