I think technologically, Star Trek is far superior to Star Wars. Weapons, shields, speed--all Star Trek. In a fleet battle, I think Star Trek would destroy Star Wars. But the Force is the great equalizer.
The Federation wouldn't be able to have an answer if they ran across a ship of Force users.
That said, Plato's Stepchildren provided a blue print, where McCoy would learn of midichlorians and give Kirk double those of Vader.
Q could certainly be a match for a Force user as well. So would Gary Mitchell, and maybe Apollo, as long as Vader couldn't figure out how to destroy the temple.
Vader, attempting to use Force Persuasion.
Spock: Your mind control abilities have no effect on me, Sir.... for I, am a Vulcan.
Kirk, confidentally striding towards Vader, swinging out his arm, knocking the saber away from Vader telekinetically)
Kirk: Not today, Vader. Not on my watch.