We have also heard of ships powered with (the help of) "paralithium" or "lithium" crystals, so there's already some variety there. (I gather that "lithium crystals" is a catchall name for all the variants, and the TOS ship was a flexi-fuel design for frontier use...)
But no, we have never had a character outright state that a specific warp vessel would operate completely without dilithium or related substances.
The Romulan artificial quantum singularity drive is certainly a candidate, but modern Romulans are still known to mine dilithium on Remus...
Timo Saloniemi
Makes sense. Although if the Feds can essentially replicate their dilithium (or regenerate it or whatnot), surely the Romulans can as well - so why bother with the mining? Why not sell factory-made dilithium instead?
Timo Saloniemi
So, do all warp drives rely on dilithium?
Early on in the Original Series, dilithium seems primarily a power-regulating material, but I'm wondering if it's grown into something unavoidably intertwined to generating warp fields at this point.
"Mudd's Women" - bypass circuits
SPOCK: The entire ship's power is feeding through one lithium crystal.
KIRK: Well, switch to bypass circuits.
SCOTT: We burned them all out when we super-heated. That jackass Walsh not only wrecked his vessel, but in saving his skin
KIRK: If it makes you feel better, Engineer, that's one jackass we're going to see skinned.
SCOTT: But it's frustrating. Almost a million gross tons of vessel depending on a hunk of crystal the size of my fist.
SPOCK: And that crystal won't hold up, not pulling all our power through it.
This would merely presume the ship has more than four crystals in place in a normal situation, so the three losses Kirk (and the audience) hears Sulu mention would not yet leave the ship dependent on a single crystal/circuit. A fourth loss out of five, or fifth out of six, taking place off screen, would match the dialogue and the known facts. This, plus the fact that Kirk's ship again can afford to lose four crystals in "Alternative Factor" and still retain main power.
If you look just at "Mudd's Women" they work with 4 circuits. Lose 4 circuits and you'll need to cutover to the bypass circuits to retain main power.
In both cases it's pretty clear it is not like TNG where the crystals are used to regulate the matter-antimatter reaction though.
As long as the Dilithium Crystal Converter Assembly was undamaged then in an emergency, you can fly around at some warp with emergency circuits that bypass the lithium/dilithium (that means that ships in TOS could warp without lithium/dilithium and it was not used to regulate the matter/antimatter reaction.) This also allowed the lithium/dilithium crystals to be pulled out and examined in "The Paradise Syndrome" without shutting down the matter/antimatter system and having to do a long cold restart.
That's one interpretation - but it's actually a somewhat convoluted one.If you look just at "Mudd's Women" they work with 4 circuits. Lose 4 circuits and you'll need to cutover to the bypass circuits to retain main power.
Think about it: the dialogue confirms loss of three dilithium circuits, leaving one, and then Scotty says all the bypass circuits were blown. We never heard that happen! Not unless the dilithium circuit is the very same thing as the bypass circuit.
it wouldn't be difficult to argue that TOS, TNG and ENT systems are basically identical save for minor engineering details, such as whether single or multiple parallel "circuits" of antimatter feed are in use.
Actually less convoluted than off-screen or parallel active-passive bypass circuits since it doesn't require re-interpreting or ignoring dialogue.
Follow the dialogue: After the 3 lithium circuits are blown, they are already concerned about the operation of the ship and have to supplement with battery power to maintain full shields on them and Mudd's ship and to operate the transporter.
And second, the bypass circuits were never in operation when the 3 lithium circuits were blown therefore they could not have been lithium circuits (otherwise they'd have spare crystals):
The destruction of the converter assembly took the bypass circuit but they are not counted towards the three lost crystal circuits since Spock didn't associate the two.
TOS engines you can pull all the dilithium and the matter-antimatter system doesn't have to be shutdown.
You can bypass the dilithium with a working converter assembly.
For a TNG-style setup you would have to have a M-AM reaction chamber for each one of the dilithium crystal circuits AND have to be able to pull each and up to all circuits without having to shutdown the M-AM system.
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