For me, the characters that totally worked were:
McCoy
Uhura
Sulu
Those that were close but still "off"
Spock
Chekov
And those that made me say WTF?
Kirk
Scotty
Kirk needs to learn to lead rather than simply being right while everyone else is wrong. Kirk made mistakes before. He should have been shown as making one or two since it was the very beginning of his career. Leading by coincidence doesn't make one a leader.
Scotty needs to calm down.
Groovy - this is my assessment too, although I am perhaps more charitable when it comes to Kirk. Pine's performance was creditable but the way the script portrayed Kirk let him down in a few places and I didn't really like the fact that bookworm Kirk had to be replaced with infallible badboy Kirk in order to be cool to a modern audience. I also didn't like Uhura snogging Spock on the transporter pad while on duty.