Some people just like to hoard collectable items and feel smug (or should that be Smaug?) that no-one else has access to them. Such people usually don't have friends. I'm thinking in particular of certain people who likely have the only copies of otherwise lost Dr Who episodes.
The last I'd read, "Enemy of the World" and "Web of Fear" were lucky; lots of ~40+ year old films, especially if poorly stored but certainly more possible if the batch of film made at the time had impure components or other problems at time of manufacture...
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