Not directly SF-related but "Rejoice in the Sun" by Joan Baez was used for the movie Silent Running:
If samples count...
I mentioned the whole album, The Rise and Fall of Ziggy Stardust and the Spiders from Mars. One of my favorite albums.I don't know if this has already been mentioned, but:
Not really a SF song, but the video is Post-Apocalyptic
From the niche band "Shakespear's Sister" (probably best known for "Stay"), an interesting ditty titled "Catwoman". Not to be confused with DC's infamous cat burglar, Selina Kyle, this tune describes an alien seductress hailing from Earth's oversized, natural satellite.
Dorky as it may seem, I can easily imagine the lead character, Mzzkiti, from my long defunct web-comic absentmindedly humming this as she goes about her duties, getting ever more "into it" until she finally notices her crew-mates staring at her near "bump'n'grind" routine.
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