As opposed to Science Officer duties. I don't mean taking the con, which Scotty and others do when required, but acting as an Exec? I think there are precious few....but maybe my memory is bad.
I suppose when Spock challenges Kirk's actions in the Conscience of the King - questioning Kirk's shifting Keven Riley's duties around, that explosive scene in Kirk's quarters when McCoy actually defends Spock to Kirk for doing "his job" might be one. I remember him going around with a clipboard in Balance of Terror, checking on ...auxiliary control? Giving Stiles and opportunity to vent some xenophobia.
But I'm curious what others remember of Spock doing an exec's duties.
I suppose when Spock challenges Kirk's actions in the Conscience of the King - questioning Kirk's shifting Keven Riley's duties around, that explosive scene in Kirk's quarters when McCoy actually defends Spock to Kirk for doing "his job" might be one. I remember him going around with a clipboard in Balance of Terror, checking on ...auxiliary control? Giving Stiles and opportunity to vent some xenophobia.
But I'm curious what others remember of Spock doing an exec's duties.