Getting to .25 lightspeed is probably a time-consuming process even for a large starship; the small shuttles may be incapable of achieving that speed within a short orbit-to-surface hop. FWIW, the runabouts of DS9 seem to go across the 1 AU distance between DS9 and Bajor at their closest in two hours (and the supposed 3 AU gulf at their most distant in six hours), so about 80 million kilometers per hour (which would include acceleration or deceleration), or about 20,000 kilometers per second on the average. Goes to show that impulse drive does allow for reasonably rapid acceleration to low relativistic speeds, but also that it isn't complete cakewalk (because the speed calculated above is not exceeded even in emergencies in DS9 - say, in "The Circle").
I sort of doubt the shuttles hit anything like 10,000 km/s when going from ship to surface, but they could well do hundreds or thousands of kilometers per second after minimal acceleration time and only have to slow down once entering the local atmosphere.
Timo Saloniemi