One thing I did notice... Kira is the ONLY Bajoran officer who ever worked on the Defiant. Now, she can be explained because she is high in the command structure of the station. I wonder if, since the Defiant is basically a classified design, Bajoran Militia were not allowed to serve on her...
IIRC, two Baron Militia crew (wearing command red rather than security brown rather than operations/infantry grey?) were also seen on the Defiant during the opening scenes of Trials and Tribble-ations escorting the Orb of Time. Odo was also on the Defiant on several occassions, though perhaps not as often as Nerys. This suggests that Militia could be assigned if necessary but as the Defiant was somewhat seperate to the DS9 command they weren't typically assigned.
Oddly, the most likely time for Dax to have qualified as a Bridge Officer (rather than just a pilot) was between The Jem'hadar and The Search (when she was promoted to LCDR) suggesting that Dax should have been the XO/1st Lt of the Defiant from Day 1 rather than Nerys. However, passing the XO role over to Worf would still make sense as he had about the same 'time in rank' and probably more bridge and command experience.