Pike is pretty hot too. I'm considering pushing him as the most attractive if he's considered eligable for TOS choices.
He's about as bad a choice for relationships as Kirk though, as he seems really emotionally unavailable. It took being completely disabled to get him to settle down. It's clear that every woman he knows is in love with him from what we see though.
I was reading the IDW omnibus of the Star Trek:Early Years comic last night, which is pretty good. It had a scene with shirtless hunky Pike getting a medical exam and his yeoman walked in on it and was so turned on she could barely speak coherently lol