Worf has made a few questionable decisions in his career, such as firing on an unidentified ship as it decloaked, sacrificing a key intelligence asset for the life of his wife, giving up his post as UFP Ambassador to the Klingon Empire for some reason, all of which would go against him.
I would say that he would be well down on the list of possible officers to command an Enterprise
Commander Austin Harris, First Officer, Deep Space Nine (by FltCpt. Bossco)
8.01 - Darkest Before Dawn
(Chapter 8 added, 12/09/2015)