I was just watching 'Hollow Pursuits' (I know, I know, an episode often maligned by fans). Brocolli strikes me as having many of the symptoms of these conditions (not picking, I have Aspergers myself). I wonder if he was written with this in mind, or not.
He kind of reminds me of an anti-Mary Sue character. Like he represents some of us, the viewers, the antisocial geeky, socially awkward types.