Oh, so we're listing B listers then? Alright.
Favorite: Edward Jellico... quite possibly the most effective captain we see. A man who will get the job done no matter the cost and a welcome deviation from the happy go lucky status quo.
Least: Jonathan Archer by virtue of he doesn't deserve to be an A lister.
Honorable mention: Erika Hernandez. Enterprise would've been better with her as the main captain.