My wife and I are going through TNG right now. She's seeing it all for the first time. We just saw the Season 6 finale 2 parter, "Descent". I think it's Descent. Data and Lore tag teaming with the Borg against the Federation. It's awesome because my wife was like "OH THAT'S WHERE HE GETS THE CHIP IN GENERATIONS!"
We've seen all the movies in order on blu ray which was really awesome. Thank you Netflix.