Okay, so 2/2 contains the same two episodes on GNP's Volume 2, albeit in the opposite order. Previously unreleased cues are:
Prognosis/The Big Question/Message From T’Pring
Vulcan Biology/Pon Farr
More Soup (maybe -- see note)
To the Death
"The Doomsday Machine"
Distress Signal/The Ship Search
The Dead Ship
The Approaching Killer
There are a lot
of discrepancies and typos on the GNP disc. The "Amok Time" program there opens with a 16-second cue called "Vulcan Fanfare" that isn't in the episode, a brash arrangement of the Courage fanfare that's definitely in Fried's brassy style of orchestration. I'm guessing this will be on Disc 5 with the library and unused cues. There's also a cue called "Marriage Council" between "T'Pring" and "Vulcan," which is distinct from the "Marriage Counseling" cue here, which is labeled as "Marriage Council II" on the CD. The "Marriage Council" cue has the same runtime as "More Soup," so it might be the same one.
Other title errors on the GNP:
"Processional" is "The Processional"
"The Ancient Combat" is "Ancient Battle"
"Approach of the Enterprise" is "Approach of Enterprise"
"Commodore Matt Decker" is "Commander Matt Decker"
"What is a Doomsday Machine?" is "What is Doomsday Machine"
"The Strange Beam" is "Strange Boom"
"The Sneaky Commodore" is "Sneaky Commodore"
"Goodbye M. Decker" is "Goodbye Mr. Decker"