Allyn Gibson wrote:
Though it's not Star Trek (or even a spy novel), I'd also recommend Greg Cox's novelization of Underworld which has a very Ian Fleming-esque flavor. Even if you've seen the movie a couple of times, the novel's quite rewarding.
If we're broadening it beyond Trek, I'll throw in Wolverine: Road of Bones
by David Mack, which is basically Wolverine as Bond.