I'm drawing a blank coming up with anybody.
Picard wore red usually and blue in Tapestry.
Riker wore red. (And gold if you count Tom Riker.)
Data wore gold usually and red in Redemption and Parallels.
Geordi wore red and gold.
Beverly wore blue.
Deanna wore blue.
Worf wore red and gold.
Tasha wore gold.
Miles wore red and gold.
...Wesley wore a uniform of sorts that had red, blue and gold on it. Is that the (trick) answer?