All these pages but no one has mentioned the short stories?
Personally, I was trying to stick with the works that I regard as part of the mostly coherent Robots/Empire/Foundation series - but even then, I, Robot
and Foundation's Friends
(which, admittedly, isn't by Asimov but just inspired by his writing) are pretty much entirely short stories.
My favorite short stories by Asimov are the ones based on his spoof paper, "The Endochronic Properties of Resublimated Thiotimoline" - but they don't seem to fit into the aforementioned continuity. (Unless maybe one chose to relate them to The End of Eternity