You certainly can't go wrong with any of his works. One thing to note though, is that he eventually tried to tie all of his stories and series together, probably one of the first attempts of world building on a big scale, and likely due to his publisher. So, his later books had more direct hints of the series being interconnected, which in my opinion felt forced as I don't think he originally intended for them to be connected. I'd enjoy the stories for what they are, good stories with lots of insight from the golden age of science fiction. The good thing is, they can be read as standalone novels.
Btw, Triumphant, there's one you didn't mention and I'm not sure if you've ever read it. It's a tribute novel set more or less in the same universe but using different names for everything since the author couldn't get permission from the estate, but it's Psychohistorical Crisis by Donald Kingsbury. It's a very good novel if you liked the Foundation series and I think it probably pays more respect and does it more justice than the second trilogy by the big 3. I highly enjoyed it.
Here's a review:
The different names for everything can take some getting used to, but the way I explained it away to myself was to have the references for things having changed over centuries and the world having evolved over time.