My favorite? Mission: Impossible II
. Runner-up? Austin Powers I
From among the official ones? Okay, okay... Casino Royale
, definitely, and while I haven't seen the last 25 minutes or so of The Living Daylights
, I enjoyed the hell out of the rest of it a while ago.
The thing about Bond movies is that most of 'em just aren't very good, and are too long to boot. I much prefer the songs.