Outside of Law & Order: SVU, Quantum Leap, and THX-1138... there's not really that much stuff worth watching. There are a handful of popular independent films though.
I don't know about that, a quick search turned up some of these fun flicks/series:
Batman: Return of the Joker
Clash of the Titans
Close Encounters of the Third Kind
Dead Like Me (series)
Hellboy (both animated movies)
Men in Black
Seaquest DSV (series)
The Italian Job
I personally think it's great and adds a lot of value to my subscription.